臺灣博碩士論文加值系統

壹、前言 1
貳、文獻回顧 3
一、頭足類 3
1. 生物分類與生理 3
2. 食用價值 3
二、重金屬之污染及衛生規範 4
1. 海洋重金屬污染 4
2. 重金屬之毒性 4
3. 衛生規範 6
三、墨囊汁 7
1. 墨囊分泌物 7
2. 取墨囊汁方法 7
3. 化學組成 8
3.1. 一般成分 8
3.2. 墨囊黑色素之生合成 8
4. 墨囊汁粉之應用 9
四、墨囊黑色素與重金屬之作用 10
1. 吸附金屬離子之形式 10
2. 脫附作用 12
2.1. 鹽酸 12
2.2. 低分子量有機酸 13
2.3. 螯合劑 13
2.4. 乙醇 13
五、重金屬之檢測方法 15
1. 火焰式原子吸收光譜法 (Flame atomic absorption spectroscopy, AAS) 15
2. 感應耦合電漿質譜法 (Inductively coupled plasma-mass spectrometry,
ICP–MS) 16
參、實驗架構 18
肆、材料與方法 18
一、材料 19
1. 墨囊汁粉 19
2. 化學藥品 19
二、方法 20
1. 一般成分分析 20
2. 水溶解度指數 (water solubility index) 22
3. 黑色素定量 22
4. 重金屬之脫附處理 23
4.1. 鹽酸 23
4.2. 檸檬酸、蘋果酸 23
4.3. EDTA CaNa2、EDTA Na2 23
4.4. 乙醇 24
5. 重金屬測定 25
5.1. 內部標準溶液 25
5.2. 標準溶液 25
5.3. 微波輔助酸消化法 (Microwave assisted acid digestion) 25
5.4. 火焰式原子吸收光譜法 (Flame atomic absorption spectroscopy, AAS) 26
5.5. 感應耦合電漿質譜法 (Inductively coupled plasma mass spectrometry, ICP–MS) 26
5.6. 重金屬含量之計算 27
5.7. 品質管制 28
6. 重金屬之脫附效率 28
7. 產率 29
8. 墨囊汁粉脫附處理後產品之風味 29
9. 統計分析 29
伍、結果與討論 30
一、墨囊汁粉之一般成分 30
二、水溶解度指數 33
三、黑色素 34
四、重金屬測定 36
1. 標準曲線 36
2. 定量極限 38
3. 墨囊汁粉重金屬含量 39
4. 脫附劑重金屬含量 40
五、脫附效果 41
1. 鹽酸 40
2. 檸檬酸、蘋果酸 45
3. EDTA CaNa2、EDTA Na2 48
4. 乙醇 54
5. 脫附效果與產率之比較 57
六、脫附處理後墨囊汁粉之風味 62
陸、結論 63
柒、參考文獻 64

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